Ice-templated synthesis of multifunctional three dimensional graphene/noble metal nanocomposites and their mechanical, electrical, catalytic, and electromagnetic shielding properties
نویسندگان
چکیده
In-situ homogeneous dispersion of noble metals in three-dimensional graphene sheets is a key tactic for producing macroscopic architecture, which is desirable for practical applications, such as electromagnetic interference shielding and catalyst. We report a one-step greener approach for developing porous architecture of 3D-graphene/noble metal (Pt and Ag) nanocomposite monoliths. The resulting graphene/noble metal nanocomposites exhibit a combination of ultralow density, excellent elasticity, and good electrical conductivity. Moreover, in order to illuminate the advantages of the 3D-graphene/noble metal nanocomposites, their electromagnetic interference (EMI) shielding and electrocatalytic performance are further investigated. The as-synthesized 3D-graphene/noble metal nanocomposites exhibit excellent EMI shielding effectiveness when compared to bare graphene; the effectiveness has an average of 28 dB in the 8.2-12.4 GHz X-band range. In the electro-oxidation of methanol, the 3D-graphene/Pt nanocomposite also exhibits significantly enhanced electrocatalytic performance and stability than compared to reduced graphene oxide/Pt and commercial Pt/C.
منابع مشابه
Improving Radar Absorbing Capability of Polystyrene Nanocomposites: Preparation and Investigation of Microwave Absorbing Properties
Microwave absorbing materials are usually designed to solve protection against electromagnetic interference in wireless communication systems and high frequency circuit mechanisms. In this research polystyrene (PS) nanocomposites containing various nano-fillers were successfully synthesized. The novelty of this work is comparing of three various nanostructures: non-metallic conductive graphene ...
متن کاملFabrication of cu based metal-organic framework / graphene Nanocomposite and study electrochemical performance in supercapacitors
High conductivity and high level of electrolyte availability are the main requirements of active materials used in supercapacitors (SCs) to achieve high electrochemical efficiency. In recent years, metal-organic frameworks (MOFs) have been used as electrode materials for SCs due to their suitability of porosity and high surface area. However, using single-component MOFs in supercapacitors resul...
متن کاملA density functional study on the mechanical properties of metal-free two-dimensional polymer graphitic Carbon-Nitride
Successful synthesis of the stable metal-free two-dimensional polymer graphitic carbon-nitride with remarkable properties has made it as one of the most promising nanostructures in many novel nanodevices, especially photocatalytic ones. Understanding the mechanical properties of nanostructures is of crucial importance. Thus, this study employs density functional theory (DFT) to obtain the mecha...
متن کاملA density functional study on the mechanical properties of metal-free two-dimensional polymer graphitic Carbon-Nitride
Successful synthesis of the stable metal-free two-dimensional polymer graphitic carbon-nitride with remarkable properties has made it as one of the most promising nanostructures in many novel nanodevices, especially photocatalytic ones. Understanding the mechanical properties of nanostructures is of crucial importance. Thus, this study employs density functional theory (DFT) to obtain the mecha...
متن کاملLearning from nature: constructing high performance graphene-based nanocomposites
After billions of years of evolution, natural materials, such as bamboo, bone, and nacre, show unique mechanical properties, due to their intrinsic hierarchical micro/nanoscale architecture and abundant interfacial interactions. This relationship between architecture, interfacial interactions, and mechanical properties of natural materials, supplies the inspiration for constructing high perform...
متن کامل